Polymer concrete is the composite material made by fully replacing the cement hydrate binders of conventional cement concrete with polymer binders or liquid resins, and is a kind of concrete-polymer composite.
For hardening of polymer concrete, most liquid resins such as thermosetting resins, methacrylic resins and tar-modified resins are polymerized at ambient or room temperature. The binder phase for polymer concrete consists only of polymers, and does not contain any cement hydrates. The aggregates are strongly bound to each other by polymeric binders.
The different ways in which the polymer is introduced into the concrete (hardened concrete) will vary widely based on the commercial objective. The polymers can be employed in concrete in different ways.
They are:
The advantages and disadvantages of polymeric binders are directly given to the polymer concrete. Accordingly, in comparison with ordinary cement concrete, its properties such as strength, adhesion, watertightness, chemical resistance, freeze-thaw durability and abrasion resistance are generally improved to a great extent by polymer replacement. Since the bond between polymeric binders and aggregates is very strong, its strength properties depend on those of the aggregates.
On the other hand, its poor thermal and fi re resistance and its large temperature dependence of mechanical properties are disadvantages due to the undesirable properties of the polymer matrix phases. Therefore, the glass transition point (or temperature) of the polymer matrix phases should be noted from the viewpoint of such thermal properties.
Thermoplastic resins generally retain their practical properties at temperatures below the glass transition point and lose them at temperatures exceeding the point, beginning to thermally decompose at somewhat higher temperatures.
The practical temperature range of the thermoplastic resins may be improved by the addition of suitable cross-linking monomers or comonomers having higher glass transition points.
Thermosetting resins do not commonly show a glass transition point, and retain their mechanical properties up to the thermal decomposition temperature. Such essential disadvantages of the polymer concrete can be considerably improved by controlling the necessary polymeric binder content by volume to a minimum.
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